Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: (a) SEM and (b and c) TEM (HAADF) images of Zr/Ce_TTp; (d–h) STEM-EDX element (Zr, Ce, S, C, and O) mapping distribution for the chemical composition analysis of Zr/Ce_TTp.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques:

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: High resolution Ce 3d (a), S 2p (b) and Zr 3d (c) XPS spectra of Zr/Ce_TTp.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques:

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: Graphical representation of the crystal structure of Zr/Ce_TTp: (a) the node; (b) portion of the packing visualized along one of the crystallographic axes. For clarity, (i) an ideal crystal structure was employed, disregarding the missing linker defects and removing the S/C–H vicariance; (ii) the clathrated DMF molecules hosted in the pores were omitted. Element colour code: C, grey; H, light grey; O, red; S, yellow; Zr/Ce, light blue. The crystal structure of Zr_TTp is not distinguishable to the eye from that of Zr/Ce_TTp.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques:

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: EXAFS fitting results shown in the direct space (a and b) and reciprocal space (c and d) for Zr_TTp (a and c) and Zr/Ce_TTp (b and d). The observed data are represented by red dots, and the result of the fit is shown in black and dark green for Zr_TTp and Zr/Ce_TTp, respectively. Fitting windows are shown in cyan. Data are shown by using a k -weight of 2.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques:

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: (a) N 2 adsorption isotherm collected at T = 77 K on Zr/Ce_TTp. Empty symbols denote the desorption branch. (b) CO 2 adsorption isotherms collected at T = 273, 298 and 323 K on Zr/Ce_TTp.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques: Adsorption

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: (a) I – t curves, (b) EIS Nyquist plots and (c) Mott–Schottky plots of Zr_TTp, Ce_TTp and Zr/Ce_TTp.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques:

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: (a) Comparison of the CO production rate of Zr/Ce_TTp and the physical mixture of Zr_TTp and Ce_TTp. (b) Recycling runs of Zr/Ce_TTp. CO gas was sampled after five hours of reaction for each cycle.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques: Comparison

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: (a) Highest occupied crystalline orbital (HOCO) and (b) lowest unoccupied crystalline orbital (LUCO) of Zr/Ce_TTp.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques:

Journal: Journal of Materials Chemistry. a

Article Title: Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal–organic framework built with a (thieno)thiophene linker

doi: 10.1039/d6ta03759c

Figure Lengend Snippet: Optimized unit cell of [CO 2 @Zr/Ce_TTp]. Main gas-framework distances reported (Å). Atom colour code: H, white; C, grey; O, red; S, yellow; Zr, turquoise; Ce, sand.

Article Snippet: UV-vis absorption diffuse reflectance spectra of H 2 TTp, Zr_TTp, Ce_TTp and Zr/Ce_TTp in the solid state were recorded from 250 to 600 nm with a Jasco V-770 spectrophotometer equipped with a 60 mm integrating sphere and a PbS detector (ISN-923), using an interval wavelength of 1 nm.

Techniques: