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Reaction mechanism of imipenem hydrolysis (via its Δ2 tautomer) by OXA-48-like enzymes , .

Journal: bioRxiv

Article Title: Hydrogen-bonding changes cause differences in imipenem breakdown activity in OXA-48 variants

doi: 10.64898/2026.01.20.700306

Figure Lengend Snippet: Reaction mechanism of imipenem hydrolysis (via its Δ2 tautomer) by OXA-48-like enzymes , .

Article Snippet: The expectation is that the imipenem pyrroline ring is in its Δ2 (enamine) tautomeric form to allow for efficient deacylation, as was confirmed for the Class A carbapenemase KPC-2 .

Techniques: