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p 44414 cl  (Cytec Industries Inc)

 
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    Structured Review

    Cytec Industries Inc p 44414 cl
    ( A ) Phase diagram of the [P 44414 ]Cl + CH 3 COOH + H 2 O system at 298 K (⬤ black) and 323 K ( ■ red). ( B ) Comparison of the experimental phase diagrams for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH or NH 4 CH 3 COO ( ▲ cyan) at 298 K.
    P 44414 Cl, supplied by Cytec Industries Inc, used in various techniques. Bioz Stars score: 86/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
    https://www.bioz.com/result/p 44414 cl/product/Cytec Industries Inc
    Average 86 stars, based on 1 article reviews
    p 44414 cl - by Bioz Stars, 2025-06
    86/100 stars

    Images

    1) Product Images from "Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids"

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    Journal: Molecules

    doi: 10.3390/molecules25235570

    ( A ) Phase diagram of the [P 44414 ]Cl + CH 3 COOH + H 2 O system at 298 K (⬤ black) and 323 K ( ■ red). ( B ) Comparison of the experimental phase diagrams for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH or NH 4 CH 3 COO ( ▲ cyan) at 298 K.
    Figure Legend Snippet: ( A ) Phase diagram of the [P 44414 ]Cl + CH 3 COOH + H 2 O system at 298 K (⬤ black) and 323 K ( ■ red). ( B ) Comparison of the experimental phase diagrams for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH or NH 4 CH 3 COO ( ▲ cyan) at 298 K.

    Techniques Used:


    Figure Legend Snippet: Quantification of phase composition for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH at 313 K (TLL—Tie Line Length). The mixture point 1* has the same initial [P 44414 ]Cl and CH 3 COOH concentration as mixture point 1 plus 2.00 wt.% NaCl.

    Techniques Used: Concentration Assay


    Figure Legend Snippet: [P 44414 ]Cl + CH 3 COOH + H 2 O system composition for all AA simulations at 323 K. All systems contain 200 [P 44414 ]Cl ion pairs and CH 3 COOH molecules with an increasing number of water molecules (n(H 2 O)).

    Techniques Used:

    ( A ) Snapshot of the equilibrated [P 44414 ]Cl + CH 3 COOH system with chloride anion and acetic acid in blue and C 4 and C 14 alkyl chains of [P 44414 ] + in purple and green respectively. ( B ) Radial distribution functions (RDFs) of the principal intermolecular interactions. The reference atom for [P 44414 ] + (CAT) was P whilst OH was taken for the carboxylic acid (AcA).
    Figure Legend Snippet: ( A ) Snapshot of the equilibrated [P 44414 ]Cl + CH 3 COOH system with chloride anion and acetic acid in blue and C 4 and C 14 alkyl chains of [P 44414 ] + in purple and green respectively. ( B ) Radial distribution functions (RDFs) of the principal intermolecular interactions. The reference atom for [P 44414 ] + (CAT) was P whilst OH was taken for the carboxylic acid (AcA).

    Techniques Used:

    ( A ) RDFs of the CH 3 COOH···Cl − with increasing water content (reference atoms for acetic acid were OH) and ( B ) corresponding coordination numbers (region 1 and 3 are monophasic whilst region 2 corresponds to the experimentally determined biphasic regime). ( C ) A representative snapshot of water-in-IL hydrated clusters for 5.1 wt.% H 2 O. ( D ) Spatial density function plots of the various system components around acetic acid for three water concentrations (Cl − —blue; [P 44414 ] + —yellow; CH 3 COOH—red; H 2 O—cyan).
    Figure Legend Snippet: ( A ) RDFs of the CH 3 COOH···Cl − with increasing water content (reference atoms for acetic acid were OH) and ( B ) corresponding coordination numbers (region 1 and 3 are monophasic whilst region 2 corresponds to the experimentally determined biphasic regime). ( C ) A representative snapshot of water-in-IL hydrated clusters for 5.1 wt.% H 2 O. ( D ) Spatial density function plots of the various system components around acetic acid for three water concentrations (Cl − —blue; [P 44414 ] + —yellow; CH 3 COOH—red; H 2 O—cyan).

    Techniques Used:


    Figure Legend Snippet: Gibbs energy of formation ( ∆ f G o ) and solubility for selected metal oxides in [P 44414 ]Cl+CH 3 COOH after 24 hr at 323 K compared to that in choline chloride ([Ch]Cl)) + CH 3 COOH (1:2) DES.

    Techniques Used: Solubility

    Viscosity of the 73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH mixture as a function of temperature.
    Figure Legend Snippet: Viscosity of the 73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH mixture as a function of temperature.

    Techniques Used:

    UV–vis spectra of the [P 44414 ]Cl + CH 3 COOH system (73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH) after metal oxide dissolution at 323 K for 24 h (blue line) and the corresponding spectra of the metal chloride salt in aqueous solution (red line). The dashed line corresponds to the spectra of the [P 44414 ]Cl + CH 3 COOH mixture in the absence of metals.
    Figure Legend Snippet: UV–vis spectra of the [P 44414 ]Cl + CH 3 COOH system (73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH) after metal oxide dissolution at 323 K for 24 h (blue line) and the corresponding spectra of the metal chloride salt in aqueous solution (red line). The dashed line corresponds to the spectra of the [P 44414 ]Cl + CH 3 COOH mixture in the absence of metals.

    Techniques Used:

    ( A ) Metal concentration in the NiMH battery leachate composed of 27.0 wt.% CH3COOH aqueous solution and in the 73.0 wt.% [P 44414 ]Cl + 27.0 wt.% CH 3 COOH mixture (t = 24 h, T = 323 K, S/L = 0.1). ( B ) Co(II) selectivity (S) in the biphasic [P 44414 ]Cl + CH 3 COOH + H 2 O from the principal metals in the NiMH leachate. The total composition of systems 1 and 1 * are provided in ; individual metal distribution coefficients are available in .
    Figure Legend Snippet: ( A ) Metal concentration in the NiMH battery leachate composed of 27.0 wt.% CH3COOH aqueous solution and in the 73.0 wt.% [P 44414 ]Cl + 27.0 wt.% CH 3 COOH mixture (t = 24 h, T = 323 K, S/L = 0.1). ( B ) Co(II) selectivity (S) in the biphasic [P 44414 ]Cl + CH 3 COOH + H 2 O from the principal metals in the NiMH leachate. The total composition of systems 1 and 1 * are provided in ; individual metal distribution coefficients are available in .

    Techniques Used: Concentration Assay



    Similar Products

    p 44414 cl  (Cytec Industries Inc)
    86
    Cytec Industries Inc p 44414 cl
    ( A ) Phase diagram of the [P 44414 ]Cl + CH 3 COOH + H 2 O system at 298 K (⬤ black) and 323 K ( ■ red). ( B ) Comparison of the experimental phase diagrams for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH or NH 4 CH 3 COO ( ▲ cyan) at 298 K.
    P 44414 Cl, supplied by Cytec Industries Inc, used in various techniques. Bioz Stars score: 86/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
    https://www.bioz.com/result/p 44414 cl/product/Cytec Industries Inc
    Average 86 stars, based on 1 article reviews
    p 44414 cl - by Bioz Stars, 2025-06
    86/100 stars
    		  Buy from Supplier

    Image Search Results


    ( A ) Phase diagram of the [P 44414 ]Cl + CH 3 COOH + H 2 O system at 298 K (⬤ black) and 323 K ( ■ red). ( B ) Comparison of the experimental phase diagrams for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH or NH 4 CH 3 COO ( ▲ cyan) at 298 K.

    Journal: Molecules

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    doi: 10.3390/molecules25235570

    Figure Lengend Snippet: ( A ) Phase diagram of the [P 44414 ]Cl + CH 3 COOH + H 2 O system at 298 K (⬤ black) and 323 K ( ■ red). ( B ) Comparison of the experimental phase diagrams for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH or NH 4 CH 3 COO ( ▲ cyan) at 298 K.

    Article Snippet: The ionic liquids [P 4444 ]Cl (95.0 wt.%), [P 44414 ]Cl (95.0 wt.%) were obtained from Cytec industries, [N 4444 ]Cl (97.0 wt.%) from Sigma-Aldrich (St. Louis, MO, USA)and [C 14 mim]Cl (98.0 wt.%) from Iolitec (Heilbronn, Germany).

    Techniques:

    Journal: Molecules

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    doi: 10.3390/molecules25235570

    Figure Lengend Snippet: Quantification of phase composition for the aqueous biphasic system composed of [P 44414 ]Cl and CH 3 COOH at 313 K (TLL—Tie Line Length). The mixture point 1* has the same initial [P 44414 ]Cl and CH 3 COOH concentration as mixture point 1 plus 2.00 wt.% NaCl.

    Article Snippet: The ionic liquids [P 4444 ]Cl (95.0 wt.%), [P 44414 ]Cl (95.0 wt.%) were obtained from Cytec industries, [N 4444 ]Cl (97.0 wt.%) from Sigma-Aldrich (St. Louis, MO, USA)and [C 14 mim]Cl (98.0 wt.%) from Iolitec (Heilbronn, Germany).

    Techniques: Concentration Assay

    ( A ) Snapshot of the equilibrated [P 44414 ]Cl + CH 3 COOH system with chloride anion and acetic acid in blue and C 4 and C 14 alkyl chains of [P 44414 ] + in purple and green respectively. ( B ) Radial distribution functions (RDFs) of the principal intermolecular interactions. The reference atom for [P 44414 ] + (CAT) was P whilst OH was taken for the carboxylic acid (AcA).

    Journal: Molecules

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    doi: 10.3390/molecules25235570

    Figure Lengend Snippet: ( A ) Snapshot of the equilibrated [P 44414 ]Cl + CH 3 COOH system with chloride anion and acetic acid in blue and C 4 and C 14 alkyl chains of [P 44414 ] + in purple and green respectively. ( B ) Radial distribution functions (RDFs) of the principal intermolecular interactions. The reference atom for [P 44414 ] + (CAT) was P whilst OH was taken for the carboxylic acid (AcA).

    Article Snippet: The ionic liquids [P 4444 ]Cl (95.0 wt.%), [P 44414 ]Cl (95.0 wt.%) were obtained from Cytec industries, [N 4444 ]Cl (97.0 wt.%) from Sigma-Aldrich (St. Louis, MO, USA)and [C 14 mim]Cl (98.0 wt.%) from Iolitec (Heilbronn, Germany).

    Techniques:

    ( A ) RDFs of the CH 3 COOH···Cl − with increasing water content (reference atoms for acetic acid were OH) and ( B ) corresponding coordination numbers (region 1 and 3 are monophasic whilst region 2 corresponds to the experimentally determined biphasic regime). ( C ) A representative snapshot of water-in-IL hydrated clusters for 5.1 wt.% H 2 O. ( D ) Spatial density function plots of the various system components around acetic acid for three water concentrations (Cl − —blue; [P 44414 ] + —yellow; CH 3 COOH—red; H 2 O—cyan).

    Journal: Molecules

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    doi: 10.3390/molecules25235570

    Figure Lengend Snippet: ( A ) RDFs of the CH 3 COOH···Cl − with increasing water content (reference atoms for acetic acid were OH) and ( B ) corresponding coordination numbers (region 1 and 3 are monophasic whilst region 2 corresponds to the experimentally determined biphasic regime). ( C ) A representative snapshot of water-in-IL hydrated clusters for 5.1 wt.% H 2 O. ( D ) Spatial density function plots of the various system components around acetic acid for three water concentrations (Cl − —blue; [P 44414 ] + —yellow; CH 3 COOH—red; H 2 O—cyan).

    Article Snippet: The ionic liquids [P 4444 ]Cl (95.0 wt.%), [P 44414 ]Cl (95.0 wt.%) were obtained from Cytec industries, [N 4444 ]Cl (97.0 wt.%) from Sigma-Aldrich (St. Louis, MO, USA)and [C 14 mim]Cl (98.0 wt.%) from Iolitec (Heilbronn, Germany).

    Techniques:

    Viscosity of the 73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH mixture as a function of temperature.

    Journal: Molecules

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    doi: 10.3390/molecules25235570

    Figure Lengend Snippet: Viscosity of the 73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH mixture as a function of temperature.

    Article Snippet: The ionic liquids [P 4444 ]Cl (95.0 wt.%), [P 44414 ]Cl (95.0 wt.%) were obtained from Cytec industries, [N 4444 ]Cl (97.0 wt.%) from Sigma-Aldrich (St. Louis, MO, USA)and [C 14 mim]Cl (98.0 wt.%) from Iolitec (Heilbronn, Germany).

    Techniques:

    UV–vis spectra of the [P 44414 ]Cl + CH 3 COOH system (73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH) after metal oxide dissolution at 323 K for 24 h (blue line) and the corresponding spectra of the metal chloride salt in aqueous solution (red line). The dashed line corresponds to the spectra of the [P 44414 ]Cl + CH 3 COOH mixture in the absence of metals.

    Journal: Molecules

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    doi: 10.3390/molecules25235570

    Figure Lengend Snippet: UV–vis spectra of the [P 44414 ]Cl + CH 3 COOH system (73.0 wt.% [P 44414 ]Cl and 27.0 wt.% CH 3 COOH) after metal oxide dissolution at 323 K for 24 h (blue line) and the corresponding spectra of the metal chloride salt in aqueous solution (red line). The dashed line corresponds to the spectra of the [P 44414 ]Cl + CH 3 COOH mixture in the absence of metals.

    Article Snippet: The ionic liquids [P 4444 ]Cl (95.0 wt.%), [P 44414 ]Cl (95.0 wt.%) were obtained from Cytec industries, [N 4444 ]Cl (97.0 wt.%) from Sigma-Aldrich (St. Louis, MO, USA)and [C 14 mim]Cl (98.0 wt.%) from Iolitec (Heilbronn, Germany).

    Techniques:

    ( A ) Metal concentration in the NiMH battery leachate composed of 27.0 wt.% CH3COOH aqueous solution and in the 73.0 wt.% [P 44414 ]Cl + 27.0 wt.% CH 3 COOH mixture (t = 24 h, T = 323 K, S/L = 0.1). ( B ) Co(II) selectivity (S) in the biphasic [P 44414 ]Cl + CH 3 COOH + H 2 O from the principal metals in the NiMH leachate. The total composition of systems 1 and 1 * are provided in ; individual metal distribution coefficients are available in .

    Journal: Molecules

    Article Title: Integrated Leaching and Separation of Metals Using Mixtures of Organic Acids and Ionic Liquids

    doi: 10.3390/molecules25235570

    Figure Lengend Snippet: ( A ) Metal concentration in the NiMH battery leachate composed of 27.0 wt.% CH3COOH aqueous solution and in the 73.0 wt.% [P 44414 ]Cl + 27.0 wt.% CH 3 COOH mixture (t = 24 h, T = 323 K, S/L = 0.1). ( B ) Co(II) selectivity (S) in the biphasic [P 44414 ]Cl + CH 3 COOH + H 2 O from the principal metals in the NiMH leachate. The total composition of systems 1 and 1 * are provided in ; individual metal distribution coefficients are available in .

    Article Snippet: The ionic liquids [P 4444 ]Cl (95.0 wt.%), [P 44414 ]Cl (95.0 wt.%) were obtained from Cytec industries, [N 4444 ]Cl (97.0 wt.%) from Sigma-Aldrich (St. Louis, MO, USA)and [C 14 mim]Cl (98.0 wt.%) from Iolitec (Heilbronn, Germany).

    Techniques: Concentration Assay