methylmagnesium chloride (Thermo Fisher)
Thermo Fisher is a verified supplier 
Thermo Fisher manufactures this product 
86
Structured Review
Thermo Fisher
methylmagnesium chloride
Methylmagnesium Chloride, supplied by Thermo Fisher, used in various techniques. Bioz Stars score: 86/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/046118%2Ejs/Methylmagnesium+chloride%2C+3M+in+THF/pm24664616-255-5-14
Average 86 stars, based on 1 article reviews
Methylmagnesium Chloride, supplied by Thermo Fisher, used in various techniques. Bioz Stars score: 86/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/046118%2Ejs/Methylmagnesium+chloride%2C+3M+in+THF/pm24664616-255-5-14
Average 86 stars, based on 1 article reviews
methylmagnesium chloride - by Bioz Stars,
2026-09
86/100 stars
Images
Related Articles
other:Article Title: Electric and Photoelectric Properties of 3,4-Ethylenedioxythiophene-Functionalized n-Si/PEDOT:PSS Junctions Article Snippet: Growing global energy demands and the need for environmentally benign energy sources have resulted in significant interest in the conversion of light energy to chemical energy by coupling light absorption to the formation of chemical bonds.. To achieve this goal efficiently and with earth-abundant materials, many different avenues have been proposed.. One such route uses silicon microwire arrays embedded in a conducting polymer membrane to separate the products and provide an avenue for charge dissipation throughout the device. Article Title: Nickel(I) monomers and dimers with cyclopentadienyl and indenyl ligands. Article Snippet: The reaction of (m-Cl)2Ni2(NHC)2 (NHC = 1,3-bis(2,6diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene (IPr) or 1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene (SIPr)) with either one equivalent of sodium cyclopentadienyl (NaCp) or lithium indenyl (LiInd) results in the formation of diamagnetic NHC supported Ni dimers of the form (m-Cp)(mCl)Ni2(NHC)2 (NHC = IPr (1 a) or SIPr (1 b) ; Cp = C5H5) or (mInd)(m-Cl)Ni2(NHC)2 (NHC = IPr (2 a) or SIPr (2 b) ; Ind = C7H9), which contain bridging Cp and indenyl ligands.. The corresponding reaction between two equivalents of NaCp or LiInd and (m-Cl)2Ni2(NHC)2 (NHC = IPr or SIPr) generates unusual 17 valence electron Ni monomers of the form (hCp)Ni(NHC) (NHC = IPr (3 a) or SIPr (3 b)) or (h-Ind)Ni(NHC) (NHC = IPr (4 a) or SIPr (4 b)), which have nonlinear geometries.. A combination of DFT calculations and NBO analysis suggests that the Ni monomers are more strongly stabilized by the Cp ligand than by the indenyl ligand, which is consistent with experimental results. Article Title: Dimethylmercury Degradation by Dissolved Sulfide and Mackinawite Article Snippet: The tube was put in an ice bath, after which Article Title: Recycling Titanocene Dichloride from the Petasis Methylenation Reaction Article Snippet: Dimethyltitanocene, introduced by Petasis for the methylenation of heteroatom-substituted carbonyl compounds, has proven to be a valuable alternative to the Tebbe reagent.. Unlike the latter, the Petasis reagent, which is easily prepared from methylmagnesium chloride and titanocene dichloride,1 is relatively airand water-stable.. The two species afford somewhat complementary chemoselectivity: the Tebbe system, which requires a Lewis base to release the Ti carbene from its precursor, shows selective reactivity toward more basic substrates (e.g., amides), while the Petasis system selects for the more electrophilic carbonyl (e.g., esters).2 When it is heated to 60-75 °C, dimethyltitanocene efficiently methylenates a wide variety of carbonyl compounds, nitriles, and even alkynes.3 A useful feature of the Petasis system is that similar reactivity can be obtained from a number of other dialkyltitanocenes, including dibenzyl and bis(trimethylsilylmethyl) derivatives.4 Petasis reagents are also tolerant of numerous functional groups, making them quite useful for natural products synthesis.5 A significant drawback to the use of such systems is the formation of the strong oxygen-titanium bond,6 which, while serving as the driving force of the reaction, has inhibited the development of versions that are catalytic in titanium. |