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dimethyl phosphite  (Thermo Fisher)


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    Structured Review

    Thermo Fisher dimethyl phosphite
    Dimethyl Phosphite, supplied by Thermo Fisher, used in various techniques. Bioz Stars score: 88/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
    https://www.bioz.com/product/043801%2E30/Diethyl+phosphite%2C+96%25/10__1007_slash_s11746___016___2820___y-49-0-11
    Average 88 stars, based on 1 article reviews
    dimethyl phosphite - by Bioz Stars, 2026-09
    88/100 stars

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    Article Title: The robust, readily available cobalt( iii ) trication [Co(NH 2 CHPhCHPhNH 2 ) 3 ] 3+ is a progenitor of broadly applicable chirality and prochirality sensing agents †Electronic supplementary information (ESI) available: CCDC 1812259 . For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01510d
    Article Snippet: The following materials were used as received: CH2Cl2 (EMD Chemicals, ACS grade), CH3OH (EMD, anhydrous, 99.8%), acetone (BDH, ACS grade), toluene (BDH, ACS grade), Co(OAc)2·4H2O (Alfa Aesar, 98%), (S,S)-dpen (NH2CHPhCHPhNH2; Oakwood or Combi blocks), activated charcoal (Acros, Norit SX 4), Na+ BArf– (BArf– = B(3,5-C6H3(CF3)2)4–; Ark Pharm, 97%), aqueous HI (Aldrich, 57 wt%, 99.9%), CoI2 (Aldrich, anhydrous, 99%), KI (Aldrich, anhydrous, 99%), NaI (EMD, >99.5%), silica gel (Silicycle SiliaFlash® F60), Celite 545 (Aldrich), (S)-1-phenethyl amine ((S)-5, TCI Chemicals, >98%, ee 97+%), 2- carbomethoxy cyclopentanone (7, TCI Chemicals, 97%), D- and L-proline (R- and S-9, Acros Organics, 99%), (S)-1-phenylethanol ((S)-10; Alfa Aesar, 98+%), (R)-10 (Alfa Aesar, 99%, ee 97+%), DL-lactide (11, Aldrich, 99%), L-lactide (S,S-11, Aldrich, 98%), (S)- and (R)-1,1'-bi-2- naphthol ((S)- and (R)-BINOL, Ark Pharm, >98%), δ-hexanolactone (12, Alfa Aesar, 98%), sty- rene oxide (16, Alfa Aesar, 98%), 1,2-propanediol (21, Aldrich, 99%), 1,2-butanediol (22, Ald- rich, 98%), 2-carbomethoxy cycloheptanone (23, Aldrich, 99%), ethyl 2-methylacetoacetate (24, Alfa Aesar, 95%), 2-acetylcyclopentanone (25, TCI Chemicals, >95%), (S)-tert-butylsulfinamide -s3- ((S)-26, Ark Pharm, 98%), (R)-tert-butylsulfinamide ((R)-26, ACS Scientific, 98%), 2-methyltet- rahydofuran (27, Aldrich, >99%), 2-bromopropionamide (30, Aldrich, 99%), 2-carboethoxy cyc- lohexanone (31, Aldrich, 95%), cyclohexene oxide (32, TCI Chemicals, 98%), methyl ethyl ke- tone (33, Aldrich, 99%), chloroacetone (34, Acros Organics, 96%), DMSO (35, BDH, 99.9%), ethyl acetate (36, Aldrich, 99.8%), isopropylamine (37, Alfa Aesar, 99%), 1-methyl-2-oxindole (39, Aldrich, 97%), ethyl acetoacetate (40, Alfa Aesar, 99%), 2-bromoethyl acetate (41, TCI Chemicals, >98%), 3-pentanone (42, Aldrich, >99%), 2-bromoacetophenone (43, Alfa Aesar, 98%), ethyl chloroacetate (44, TCI Chemicals, 98%), benzyl carbamate (45, Alfa Aesar, 99%), ethyl cyanoacetate (46, TCI Chemicals, >98%), propionamide (47, TCI Chemicals, >98%), di- methyl malonates (Alfa Aesar, 98%), sec-butylbenzene (TCI Chemicals, >99%), nitroethane (Al- drich, >98%), 5-hydroxymethyl-2-pyrrolidinone (Chem-Impex International, 98.5%), propioni- trile (Acros Organics, 99%), propionic acid (Alfa Aesar, 99%), methyl isovalerate (Aldrich, >98%), diethyl phosphite (Alfa Aesar, 96%), and tetrahydrofuran (Aldrich, >99%).

    Article Title: Chiral solvating agents
    Article Snippet: The following materials were used as received: CH2Cl2 (EMD Chemicals, ACS grade), CH3OH (EMD, anhydrous, 99.8%), acetone (BDH, ACS grade), toluene (BDH, ACS grade), Co(OAc)2.4H2O (Alfa Aesar, 98%), (S,S)-dpen (NH2CHPhCHPhNH2; Oakwood or Combi blocks), activated charcoal (Acros, Norit SX 4), Nat BArf− (BArf−═B(3,5-C6H3(CF3)2)4−; Ark Pharm, 97%), aqueous HI (Aldrich, 57 wt %, 99.9%), CoI2 (Aldrich, anhydrous, 99%), KI (Aldrich, anhydrous, 99%), NaI (EMD, >99.5%), silica gel (Silicycle SILIAFLASH® F60), Celite 545 (Aldrich), (S)-1-phenethyl amine ((S)-5, TCI Chemicals, >98%, ee 97+%), 2-carbomethoxy cyclopentanone (7, TCI Chemicals, 97%), D- and L-proline (R- and S-9, Acros Organics, 99%), (S)-1-phenylethanol ((S)-10; Alfa Aesar, 98+%), (R)-10 (Alfa Aesar, 99%, ee 97+%), DL-lactide (11, Aldrich, 99%), L-lactide (S,S-11, Aldrich, 98%), (S)- and (R)-1,1′-bi-2-naphthol ((S)- and (R)-BINOL, Ark Pharm, >98%), 6-hexanolactone (12, Alfa Aesar, 98%), styrene oxide (16, Alfa Aesar, 98%), 1,2-propanediol (21, Aldrich, 99%), 1,2-butanediol (22, Aldrich, 98%), 2-carbomethoxy cycloheptanone (23, Aldrich, 99%), ethyl 2-methylacetoacetate (24, Alfa Aesar, 95%), 2-acetylcyclopentanone (25, TCI Chemicals, >95%), (S)-tert-butylsulfinamide ((S)-26, Ark Pharm, 98%), (R)-tert-butylsulfinamide ((R)-26, ACS Scientific, 98%), 2-methyltetrahydofuran (27, Aldrich, >99%), 2-bromopropionamide (30, Aldrich, 99%), 2-carboethoxy cyclohexanone (31, Aldrich, 95%), cyclohexene oxide (32, TCI Chemicals, 98%), methyl ethyl ketone (33, Aldrich, 99%), chloroacetone (34, Acros Organics, 96%), DMSO (35, BDH, 99.9%), ethyl acetate (36, Aldrich, 99.8%), isopropylamine (37, Alfa Aesar, 99%), 1-methyl-2-oxindole (39, Aldrich, 97%), ethyl acetoacetate (40, Alfa Aesar, 99%), 2-bromoethyl acetate (41, TCI Chemicals, >98%), 3-pentanone (42, Aldrich, >99%), 2-bromoacetophenone (43, Alfa Aesar, 98%), ethyl chloroacetate (44, TCI Chemicals, 98%), benzyl carbamate (45, Alfa Aesar, 99%), ethyl cyanoacetate (46, TCI Chemicals, >98%), propionamide (47, TCI Chemicals, >98%), dimethyl malonates (Alfa Aesar, 98%), sec-butylbenzene (TCI Chemicals, >99%), nitroethane (Aldrich, >98%), 5-hydroxymethyl-2-pyrrolidinone (Chem-Impex International, 98.5%), propionitrile (Acros Organics, 99%), propionic acid (Alfa Aesar, 99%), methyl isovalerate (Aldrich, >98%), diethyl phosphite (Alfa Aesar, 96%), and tetrahydrofuran (Aldrich, >99%).

    Article Title: Tribological Properties of Limonene Bisphosphonates
    Article Snippet: Limonene was chemically modified by reacting it with dialkyl phosphites of varying alkyl structures under inert atmosphere in the presence of free radical initiators.. The reaction gave a mixture of monoand di-adduct products and was optimized to produce only the di-adduct product limonene bisphosphonate by forcing both limonene double bonds to react completely.. The product mixture was carefully characterized using a combination of gas chromatography–mass spectroscopy, infrared spectroscopy, and nuclear magnetic resonance spectroscopy (H, C, P).

    Article Title: Radical-Initiated Reaction of Methyl Linoleate with Dialkyl Phosphites
    Article Snippet: Organic compounds containing phosphorus have applications in many areas, including lubricants, lubricant additives, flame retardants, antimicrobial agents, herbicides, and plasticizers.. Bio-based phosphorus-containing materials were synthesized in the past and were reported as having desirable qualities as lubricant additives [1, 2], plasticizers [3], and antimicrobial agents [4].. Phosphate groups were introduced into a biobased structure by reacting dialkyl phosphate with epoxidized fatty acid methyl esters [5] or epoxidized soybean oil [6].

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    Article Title: Novel phenylboronic acid derivatives containing phosphorous and nitrogen as lubricant additives: Synthesis, characterization, and tribological behaviors
    Article Snippet: Three phenylboronic acid derivatives containing phosphorous and nitrogen with chlorine (BNP1), methyl (BNP2), and nitro (BNP3) were successfully prepared and applied to evaluate the tribological behaviors as additives in liquid paraffin.. Three derivatives exhibited high thermal stability.. The tribological tests indicated that three derivatives lead to a substantial improvement in anti-friction and anti-wear properties of liquid paraffin.



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