tert butyl chloro dimethylsilane (Chem Impex International)

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Chem Impex International tert butyl chloro dimethylsilane
Tert Butyl Chloro Dimethylsilane, supplied by Chem Impex International, used in various techniques. Bioz Stars score: 95/100, based on 6 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/00614/tert-Butyldimethylsilyl+chloride/pm39656131-46-6-11
Average 95 stars, based on 6 article reviews

tert butyl chloro dimethylsilane - by Bioz Stars, 2026-09

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Article Title: Anion-Controlled Positional Switching of a Phenyl Group about the Dinuclear Core of a AuSb Complex.
Article Snippet: As part of our continuing interest in redox-active, anion-responsive main-group transition-metal platforms, we have investigated the effect of chloride by fluoride anion substitution on the core structure of a dinuclear AuSb platform.. Starting from [(o(iPr2P)C6H4)2Cl2SbPh]AuCl (2) in which the antimony-bound phenyl group is positioned trans to the gold atom, we found that the introduction of fluoride anions, as in [(o-(iPr2P)C6H4)2F2SbPh]AuCl (3) and [(o-(iPr2P)C6H4)2ClFSbPh]AuCl (4), produces structures in which the phenyl group switches to a perpendicular direction with respect to the gold atom.. Replacement of the goldbound chloride anion in 3 by a fluoride anion can be achieved by successive treatment with TlPF6 and [nBu4N][Ph3SiF2].

Article Title: Programming Surface Motility and Modulating Physiological Behaviors of Bacteria via Biosurfactant-Mimetic Polyurethanes.
Article Snippet: 4-Dimethylaminopyridine (DMAP), 1-ethyl3-(3-(dimethylamino)propyl) carbodiimide (EDC), and tert-butyl(chloro) dimethylsilane were obtained from Chem-Impex Int’l.

Article Title: Programming Surface Motility and Modulating Physiological Behaviors of Bacteria via Biosurfactant-Mimetic Polyurethanes
Article Snippet: 4-Dimethylaminopyridine (DMAP), 1-ethyl-3-(3-(dimethylamino)propyl) carbodiimide (EDC), and tert -butyl(chloro) dimethylsilane were obtained from Chem-Impex Int’l.

Article Title: Genotoxic C8-Arylamino-2'-deoxyadenosines Act as Latent Alkylating Agents to Induce DNA Interstrand Cross-Links.
Article Snippet: 4-Aminobiphenyl, 2-aminofluorene, and benzyl chloride (BzCl) were purchased from Alfa Aesar (Haverhill, MA, USA). tert-Butyldimethylsilyl chloride (TBSCl) and 4,4’-dimethoxytrityl chloride (DMTrCl) were purchased from Chem-Impex (Wood Dale, IL, USA).

Article Title: Synergism between Rifampicin and Cationic Polyurethanes Overcomes Intrinsic Resistance of Escherichia coli .
Article Snippet: Antibiotic-resistant Gram-negative bacteria are emergent pathogens, causing millions of infections worldwide.. While there are several classes of antibiotics that are effective against Gram-positive bacteria, the outer membrane (OM) of Gramnegative bacteria excludes high-molecular-weight hydrophobic antibiotics, making these species intrinsically resistant to several classes of antibiotics, including polyketides, aminocoumarins, and macrolides.. The overuse of antibiotics such as β-lactams has also promoted the spread of resistance genes throughout Gram-negative bacteria, including the production of extended spectrum β-lactamases (ESBLs).

Article Title: Umpolung Synthesis of 1,3-Amino Alcohols: Stereoselective Addition of 2-Azaallyl Anions to Epoxides.
Article Snippet: The following chemicals were used as received: acetone (Fisher); allylamine (Sigma-Aldrich); trans-anethole (Sigma-Aldrich); benzaldehyde (Sigma-Aldrich); benzhydrylamine (Alfa Aesar); benzophenone imine (Chem-Impex); benzylamine (Acros); boron trifluoride diethyl etherate (Alfa Aesar); 2-bromobenzaldehyde (Ark Pharm); 3-bromobenzaldehyde (Chem-Impex); 4- bromobenzylamine (Ark Pharm); t-butyldimethylsilylchloride (Sigma-Aldrich); 3- chloroperoxybenzoic acid-50% (Alfa Aesar); cinnamyl alcohol (Alfa Aesar); copper iodide (Alfa Aesar); 4-cyanobenzaldehyde (Chem-Impex); cyclohexene oxide (Sigma-Aldrich); diethyl azodicarboxylate (Sigma-Aldrich); dilithium tetrachlorocuprate (II) solution, 0.1 M in THF (Sigma-Aldrich); dimethoxypropane (Acros); 4-dimethylaminopyridine (Alfa Aesar); dimethoxymethane (Sigma-Aldrich); 1;2-epoxyhexane (Fisher); ethylenediaminetetraacetic acid (TCI America); ethylmagnesium bromide, 3M in THF (Sigma-Aldrich); D-fructose (Acros); imidazole (Sigma-Aldrich); isobutylmagnesium bromide, 2M in Et2O (Acros); lithium bis(trimethylsilyl)amide (Sigma-Aldrich); 4-methoxybenzylamine (Sigma-Aldrich); 2- methylbenzylamine (Sigma-Aldrich); 2-methyl-2-butene (TCI); α-methyl styrene (Alfa Aesar); trans-β-methyl styrene (Acros); Oxone®; 50% (Sigma-Aldrich); pentane-3-one (Sigma-Aldrich) perchloric acid (Acros); phenylmagnesium bromide, 1M in THF (Sigma-Aldrich); potassium carbonate (Alfa Aesar); propargyl alcohol (Alfa Aesar); 3-pyridinecarboxaldehyde (TCI America); pyridine chlorochromate (Alfa Aesar); sodium acetate (Sigma-Aldrich); sodium bicarbonate (BDH); sodium hydroxide (BDH); sodium perborate tetrahydrate (Sigma-Aldrich); sulfur trioxide pyridine complex (Sigma-Aldrich); styrene (Sigma-Aldrich); tetrabutylammonium hydrogen sulfate (TCI America);o-tolualdehyde (Sigma-Aldrich); ptoluenesulfonic acid (Alfa Aesar); trans-stilbene (Alfa Aesar); cis-stilbene oxide (SigmaAldrich); trans-stilbene oxide (TCI America); 3-trifluorobenzylamine (Sigma-Aldrich); 4- trifluoromethylbenzaldehyde (Matrix); triphenylcarbenium tetrafluoroborate (Acros); triphenylphosphine (Alfa Aesar).

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Article Title: Sporopollenin-inspired design and synthesis of robust polymeric materials
Article Snippet: 1,8-octanediol (TCI, >99%), 1,10-decanediol (TCI, >95%), 1,12-dodecanediol (Acrōs, 99%), 1,14-tetradecanediol (CombiBlocks, 97%), 1,16-hexadecanediol (TCI, >95%), Dess-Martin periodinane (Oakwood, 95%), polyvinyl alcohol (Mw,avg = 31-50k, Sigma Aldrich, 98–99% hydrolyzed), polyvinyl alcohol (Mw,avg = 85-124k, Sigma Aldrich, >99% hydrolyzed), polyvinyl alcohol (Mw,avg = 89-98k, Sigma Aldrich, >99% hydrolyzed), polyvinyl alcohol (Mw,avg = 146-186k, Sigma Aldrich >99% hydrolyzed), cyclohexanone (Acrōs, >99%), cyclohexylamine (TCI, >99%), n-butyllithium (Acrōs, 2.45 M), diisopropylamine (Spectrum, >99%), 11-bromo-1-undecene (Oakwood, 95%), sodium (meta)periodate (BTC, 98%), potassium permanganate (J.T. .. Baker, 99.4%), methyl iodide (Alfa Aesar, >98%), potassium carbonate (Sigma Aldrich, 99%), meta-chloroperbenzoic acid (Sigma Aldrich, <77%), sodium methoxide (Acrōs, >99%), 4-dimethylaminopyridine (Acrōs, 99%), N,N’dicyclohexylcarbodiimide (TCI, >98%), lithium borohydride (Strem, 95%), tetrabutylammonium fluoride (Oakwood, 1 M in THF), triethylamine (Acrōs, 99%), sulfur trioxide pyridine complex (TCI, >95%), coumaric acid (TCI, >98%), tert-butyldimethylsilyl chloride (Chem-Impex, 99%), imidazole (Sigma Aldrich, 99%), ethane thiol (Sigma Aldrich, 97%), boron trifluoride diethyl etherate (Sigma Aldrich, >46.5% BF3 basis), acetic acid (Spectrum, >99.7%), concentrated sulfuric acid (EMD Millipore, 95%), 4 Å molecular sieves (Sigma Aldrich), ammonium chloride (Mallinckrodt, 99.5%), sodium sulfate (Sigma Aldrich, >99%), Celite (Fisher), sodium bicarbonate (Mallinckrodt, >99.7%), conc. hydrochloric acid (Macron, 36.5–38.0%), sodium hydroxide (AmericanBio, 97%), sodium chloride (EMD Millipore, 99.5%), dicholoromethane (Fisher, >99.5%), dimethylsulfoxide (Fisher, >99.9%), diethyl ether (Fisher, >99.9%), tetrahydrofuran (Acrōs, >99.5%, extra dry, stabilized with BHT), acetone (Fisher, >99.5%), water (distilled), petroleum ether (Fisher, 36–60 °C Fraction), hexanes (Fisher, 98.5%), ethyl acetate (Fisher, 99.5%), dimethylformamide (Acrōs, 99.8%), chloroform (EMD Millipore, >99.8%), methanol (EMD Millipore, 99.9%), and dioxane (Acrōs, 99.8%) were used as received without further purification unless otherwise noted. .. Column chromatography was conducted using Silicycle SiliaFlash P60 SiO2 (40–63 μm).

Article Title: Sporopollenin-inspired design and synthesis of robust materials
Article Snippet: 1,8-octanediol (TCI, >99%), 1,10-decanediol (TCI, >95%), 1,12-dodecanediol (Acrōs, 99%), 1,14-tetradecanediol (CombiBlocks, 97%), 1,16-hexadecanediol (TCI, >95%), Dess-Martin periodinane (Oakwood, 95%), polyvinyl alcohol (Mw,avg = 31-50k, Sigma Aldrich, 98–99% hydrolyzed), polyvinyl alcohol (Mw,avg = 85-124k, Sigma Aldrich, >99% hydrolyzed), polyvinyl alcohol (Mw,avg = 89-98k, Sigma Aldrich, >99% hydrolyzed), polyvinyl alcohol (Mw,avg = 146-186k, Sigma Aldrich >99% hydrolyzed), cyclohexanone (Acrōs, >99%), cyclohexylamine (TCI, >99%), n-butyllithium (Acrōs, 2.45 M), diisopropylamine (Spectrum, >99%), 11-bromo-1-undecene (Oakwood, 95%), sodium (meta)periodate (BTC, 98%), potassium permanganate (J.T. .. Baker, 99.4%), methyl iodide (Alfa Aesar, >98%), potassium carbonate (Sigma Aldrich, 99%), meta-chloroperbenzoic acid (Sigma Aldrich, <77%), sodium methoxide (Acrōs, >99%), 4-dimethylaminopyridine (Acrōs, 99%), N,N’-dicyclohexylcarbodiimide (TCI, >98%), lithium borohydride (Strem, 95%), tetrabutylammonium fluoride (Oakwood, 1 M in THF), triethylamine (Acrōs, 99%), sulfur trioxide pyridine complex (TCI, >95%), coumaric acid (TCI, >98%), tert-butyldimethylsilyl chloride (Chem-Impex, 99%), imidazole (Sigma Aldrich, 99%), ethane thiol (Sigma Aldrich, 97%), boron trifluoride diethyl etherate (Sigma Aldrich, >46.5% BF3 basis), acetic acid (Spectrum, >99.7%), concentrated sulfuric acid (EMD Millipore, 95%), 4 Å molecular sieves (Sigma Aldrich), ammonium chloride (Mallinckrodt, 99.5%), sodium sulfate (Sigma Aldrich, >99%), Celite (Fisher), sodium bicarbonate (Mallinckrodt, >99.7%), conc. hydrochloric acid (Macron, 36.5– 38.0%), sodium hydroxide (AmericanBio, 97%), sodium chloride (EMD Millipore, 99.5%), dicholoromethane (Fisher, >99.5%), dimethylsulfoxide (Fisher, >99.9%), diethyl ether (Fisher, >99.9%), tetrahydrofuran (Acrōs, >99.5%, extra dry, stabilized with BHT), acetone (Fisher, >99.5%), water (distilled), petroleum ether (Fisher, 36–60 °C Fraction), hexanes (Fisher, 98.5%), ethyl acetate (Fisher, 99.5%), dimethylformamide (Acrōs, 99.8%), chloroform (EMD Millipore, >99.8%), methanol (EMD Millipore, 99.9%), and dioxane (Acrōs, 99.8%) were used as received without further purification unless otherwise noted. .. Column chromatography was conducted using Silicycle SiliaFlash P60 SiO2 (40–63 μm).

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